Morphological changes and multicolor photochromism of Ag nanoparticles deposited on single-crystalline TiO2 surfaces

被引:169
作者
Matsubara, Kazuki
Tatsuma, Tetsu [1 ]
机构
[1] Univ Tokyo, Inst Ind Sci, Meguro Ku, Tokyo 1538505, Japan
[2] Japan Sci & Technol Agcy, PRESTO, Saitama 3320012, Japan
关键词
D O I
10.1002/adma.200602823
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Silver gets fat and thin: Ag nanoparticles photocatalytically deposited on rutile TiO2 single crystals exhibit multicolor photochromism. Under monochromatic visible light, particles resonant with the light are photoelectrochemically dissolved, and re-deposited on the TiO2 substrate or non-resonant particles. These size-selective dissolution and growth are responsible for the wavelength-dependent color changes.
引用
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页码:2802 / +
页数:6
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