Synthesis and characterization of water soluble viologen linked zinc porphyrins

被引:20
作者
Amao, Y [1 ]
Kamachi, T [1 ]
Okura, I [1 ]
机构
[1] TOKYO INST TECHNOL,DEPT BIOENGN,MIDORI KU,YOKOHAMA,KANAGAWA 226,JAPAN
关键词
viologen; viologen linked zinc porphyrins; photosynthesis;
D O I
10.1016/1010-6030(96)04353-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A series of water soluble viologen linked zinc porphyrins (ZnP(CnV)(4),n = 3-6) were synthesized. Four viologens are connected with the zinc porphyrin via a methylene chain (-(CH2)(n)-: n = 3-6) in these compounds. The photochemical and electrochemical properties of ZnP(CnV)(4) were measured and the quenching process of the photoexcited porphyrin by the binding viologen was discussed.
引用
收藏
页码:59 / 64
页数:6
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