Structure and magnetism of a new pyrazolate bridged iron(II) spin crossover complex displaying a single HS-HS to LS-LS transition

被引：88

作者：

Leita, BA

Moubaraki, B

Murray, KS

Smith, JP

Cashion, JD

机构：

[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

[2] Sch Phys & Mat Engn, Clayton, Vic 3800, Australia

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 02期

关键词：

D O I：

10.1039/b311818e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The dinuclear iron(II) complex [(pypzH)(NCSe)Fe(mu-pypz)(2)-Fe(NCSe)(pypzH)].2H(2)O displays a single, sharp spin crossover transition between the [HS-HS] and [LS-LS] states and is structurally characterised above and below the T-1/2 = 225 K value.

引用

页码：156 / 157

页数：2

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