A new type of supramolecular entanglement in the silver(I) coordination polymer [Ag2(bpethy)5](BF4)2 [bpethy = 1,2-bis(4-pyridyl)ethyne]

被引:183
作者
Carlucci, L
Ciani, G
Proserpio, DM
机构
[1] Dipartimento Chim Strutturale & Stereochim Inorga, I-20133 Milan, Italy
[2] Ctr CNR, I-20133 Milan, Italy
关键词
D O I
10.1039/a809361j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The polymeric compound [Ag-2(bpethy)(5)](BF4)(2), obtained from AgBF4 and 1,2-bis(4-pyridyl)ethyne (bpethy) in molar ratio 1:3, contains infinite molecular ladder motifs with monodentate ligands as sidearms on both sides, that are threaded through the squares of adjacent polymeric units in a mutual relationship, to give infinite 'polythreaded' bidimensional layers.
引用
收藏
页码:449 / 450
页数:2
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