Luminescence monitoring of lanthanide catalysts for diene polymerization

被引：5

作者：

Bulgakov, RG ^{[1
]}

Kuleshov, SP

Zuzlov, AN

Vafin, RR

Rusakov, SV

Mullagaliev, IR

Dzhemilev, UM

Monakov, YB

机构：

[1] Russian Acad Sci, Ufa Sci Ctr, Acad Sci Bashkortostan, Inst Petrochem & Catalysis, Ufa 450075, Bashkortostan, Russia

[2] Russian Acad Sci, Ufa Sci Ctr, Inst Organ Chem, Ufa 450054, Bashkortostan, Russia

来源：

KINETICS AND CATALYSIS | 2003年 / 44卷 / 05期

关键词：

D O I：

10.1023/A:1026162626898

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Changes in the luminescence characteristics of Tb3+ and Ce3+ lanthanide ions in the interaction of LnCl(3) . 3(BuO)(3)PO Complexes with iso-Bu3Al in the absence and presence of piperylene were studied. As a result, a new luminescence approach was proposed to study reaction mechanisms in the synthesis of lanthanide catalysts for diene polymerization.

引用

页码：718 / 725

页数：8

共 27 条

[1]

Bochkarev M.N., 1989, ORGANIC DERIVATIVES, P232

[2]

Brauer G., 1975, HDB PRAPARATIVEN ANO

[3] LUMINESCENCE OF ORGANOMETALLIC LANTHANIDE COMPOUNDS - TETRAHYDROFURAN ADDUCTS OF TRICYCLOPENTADIENYLTERBIUM(III) AND TRIS(METHYLCYCLOPENTADIENYL)TERBIUM(III) [J].

BRITTAIN, HG ;

MEADOWS, JH ;

EVANS, WJ .

ORGANOMETALLICS, 1983, 2 (11) :1661-1665

[4] Dehydration of LnCl3•6H2O (Ln = Tb, Nd, Dy) in the reaction with i-Bu3Al, Et3Al, Et2AlCl, EtAlCl2 and formation of the complexes LnCl3•3(BuO)3PO [J].

Bulgakov, RG ;

Kuleshov, SP ;

Zuzlov, AN ;

Mullagaleev, IR ;

Khalilov, LM ;

Dzhemilev, UM .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 636 (1-2) :56-62

[5]

CHARLOT G, 1961, METHODES CHIM ANAL

[6]

CHIRKOV NM, 1976, POLIMERIZATSIYA KOMP, P32

[7]

ERMOLAEV VL, 1994, USP KHIM+, V63, P962

[8]

GADELEVA KK, 1985, THESIS I ORG CHEM

[9]

KORNEEV NN, 1979, KHIM TEKHNOLOGIYA AL, P246

[10]

KOROVIN SS, 1975, ZH NEORG KHIM+, V20, P908

← 1 2 3 →