Two stable hydrides of antimony:: RSbH2 and R(H)Sb-Sb(H)R (R = (Me3Si)2CH)

被引：34

作者：

Balázs, G ^{[1
]}

Breunig, HJ ^{[1
]}

Lork, E ^{[1
]}

Offermann, W ^{[1
]}

机构：

[1] Univ Bremen, Fachbereich Chem 2, D-28334 Bremen, Germany

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 13期

关键词：

D O I：

10.1021/om010177h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

RSbH2 (1) and R(H)Sb-Sb(H)R (2) (R = (Me3Si)(2)CH) are formed in good yield by reactions of RSbCl2 with LiAlH4. The crystal structure of 2 consists of molecules in the meso form.

引用

页码：2666 / 2668

页数：3

共 16 条

[1] THE STRUCTURE OF TETRAMETHYLDISTIBINE [J].

ASHE, AJ ;

LUDWIG, EG ;

OLEKSYSZYN, J ;

HUFFMAN, JC .

ORGANOMETALLICS, 1984, 3 (02) :337-338

[2] TRIMETHYLSILYL DERIVATIVES OF VB-ELEMENTS .6. SYNTHESIS, MOLECULAR AND CRYSTAL-STRUCTURE OF TETRAKIS(TRIMETHYLSILYL)DISTIBINE COMPARED WITH TETRAPHENYLDISTIBINE [J].

BECKER, G ;

FREUDENBLUM, H ;

WITTHAUER, C .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1982, 492 (09) :37-51

[3] The synthesis and characterization of isobutylantimony compounds [J].

Berry, A .

POLYHEDRON, 1999, 18 (20) :2609-2615

[4] Sb8R4, R = (Me3Si)(2)CH - A polycyclic organostibane [J].

Breunig, HJ ;

Rosler, R ;

Lork, E .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (20) :2237-2238

[5]

BREUNIG HJ, 1997, ANGEW CHEM, V109, P2333

[6]

CARMALT CJ, 1998, CHEM ARSENIC ANTIMON, P20

[7]

COTTON FA, 1988, ADV INORG CHEM, P390

[8] [MES2SBCU(PME3)2]2 - THE 1ST CU(I) ANTIMONIDE [J].

COWLEY, AH ;

JONES, RA ;

NUNN, CM ;

WESTMORELAND, DL .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (08) :1018-1019

[9]

DEUTEN KV, 1980, CRYST STRUCT COMMUN, V9, P167

[10]

MUNDT O, 1984, Z NATURFORSCH B, V39, P317

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