SPLITT cell separation of polydisperse suspended particles of environmental interest

被引:30
作者
Dondi, F
Contado, C
Blo, G
Martin, SG
机构
[1] Univ Ferrara, Dept Chem, I-44100 Ferrara, Italy
[2] Univ Santiago de Compostela, Dept Analyt Chem Nutr & Bromatol, Lugo, Spain
关键词
SPLITT cell; density; clay particles; sedimentation; SedFFF;
D O I
10.1007/BF02467594
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Split-new thin (SPLITT) cell, continuous two-way separation has been investigated for the separation of particulate matter of environmental interest. The basic SPLITT cell operation equation is reconsidered and the effects of the particle porosity, dimension, shape and density are discussed. Suspensions of porous silica, kaolin and montmorillonite in the submicron to micron diameter range were separated by means of the SPLITT cell with appropriate carrier composition. The results of the separations were checked by use of optical and scanning-electron microscopy and are discussed with reference to the basic equations for SPLITT cell working conditions. Optimum results were in agreement with the theoretical expressions as long as the pertinent SPLITT separation expression was employed. Quantitative results from SPLITT cell separations were compared with those obtained by the classical static sedimentation procedure, the agreement and discrepancies found ape discussed.
引用
收藏
页码:643 / 654
页数:12
相关论文
共 30 条
[1]  
Allen T., 1981, PARTICLE SIZE MEASUR, V3rd
[2]   Entropic contribution to the retention of nonspherical particles in field-flow fractionation [J].
Beckett, R ;
Giddings, JC .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1997, 186 (01) :53-59
[3]   CHARACTERIZATION OF LOW-DENSITY POLYBUTADIENE LATEXES BY SEDIMENTATION FIELD-FLOW FRACTIONATION [J].
BLANDA, M ;
RESCHIGLIAN, P ;
DONDI, F ;
BECKETT, R .
POLYMER INTERNATIONAL, 1994, 33 (01) :61-69
[4]  
Blo G, 1995, CHROMATOGRAPHIA, V41, P715
[5]  
Bohrem CF, 1983, ABSORPTION SCATTERIN
[6]   Characterisation of River Po particles by sedimentation field-flow fractionation coupled to GFAAS and ICP-MS [J].
Contado, C ;
Blo, G ;
Fagioli, F ;
Dondi, F ;
Beckett, R .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1997, 120 (1-3) :47-59
[7]   Separation of particulate environmental samples by SPLITT fractionation using different operating modes [J].
Contado, C ;
Dondi, F ;
Beckett, R ;
Giddings, JC .
ANALYTICA CHIMICA ACTA, 1997, 345 (1-3) :99-110
[8]  
Dondi F, 1997, ANN CHIM-ROME, V87, P113
[9]  
Everett D. H., 1988, BASIC PRINCIPLES COL, DOI DOI 10.1039/9781847550200
[10]   COLLOID CHARACTERIZATION BY SEDIMENTATION FIELD-FLOW FRACTIONATION .1. MONODISPERSE POPULATIONS [J].
GIDDINGS, JC ;
KARAISKAKIS, G ;
CALDWELL, KD ;
MYERS, MN .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1983, 92 (01) :66-80