Iodination of organotrifluoroborates: synthesis of vinyl and alkynyl iodides

被引：35

作者：

Kabalka, GW

Mereddy, AR

机构：

[1] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA

[2] Univ Tennessee, Dept Radiol, Knoxville, TN 37996 USA

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 07期

基金：

美国国家卫生研究院;

关键词：

iodination; organotrifluoroborates; vinyl iodides; alkynyl iodides;

D O I：

10.1016/j.tetlet.2003.12.050

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Vinyl- and alkynyltrifluoroborates are rapidly converted to vinyl and alkynyl iodides under mild conditions using sodium iodide in the presence of chloramine-T. The reaction is stereospecific and proceeds in excellent yield. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：1417 / 1419

页数：3

共 31 条

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