Facile Synthesis of 1,1′-Dialkylisoindigos through Deoxygenation Reaction of Isatins and Tris(diethylamino)phosphine

被引：39

作者：

Bogdanov, Andrei V. ^{[1
]}

Mironov, Vladimir F. ^{[1
]}

Musin, Lenar I. ^{[1
]}

Musin, Rashid Z. ^{[1
]}

机构：

[1] KSC RAS, AE Arbuzov Organ & Phys Chem Inst, Kazan 420088, Russia

来源：

SYNTHESIS-STUTTGART | 2010年 / 19期

关键词：

carbenes; deoxygenation; heterocycles; regioselectivity; phosphorus; GLYCOSYL-ISOINDIGO DERIVATIVES; ACENAPHTHENEQUINONE;

D O I：

10.1055/s-0030-1258219

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A convenient one-step synthesis of symmetrical 1,1'-dialkyl derivatives of isoindigo is described.

引用

页码：3268 / 3270

页数：3

共 17 条

[1]

BANERJI A, 1994, INDIAN J CHEM B, V33, P532

[2] Isatin Derivatives in the Reaction with Phosphorous Hexaethyltriamide. A New Approach to the Synthesis of Isoindigo Derivatives [J].

Bogdanov, A. V. ;

Mironov, V. F. ;

Musin, L. I. ;

Buzykin, B. I. ;

Konovalov, A. I. .

RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2008, 78 (10) :1977-1979

[3] Deoxygenation of acenaphthenequinone with hexaethylphosphorous triamide: An efficient method of synthesis of biacenaphthylidenedione [J].

Bogdanov, AV ;

Mironov, VF ;

Buzykin, BI ;

Konovalov, AI .

RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2005, 75 (05) :825-826

[4] Heterocyclic carbenes: Synthesis and coordination chemistry [J].

Hahn, F. Ekkehardt ;

Jahnke, Mareike C. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (17) :3122-3172

[5]

HARLEYMASON J, 1958, J CHEM SOC, P4782

[6]

Islam M. R., 2005, J BANGLADESH CHEM SO, V18, P1

[7]

KORMACHEV VV, 1992, PREPARATIVE PHOSPHOR

[8] Synthesis and study of 3-(triphenylphosphoranylidene)-2,3-dihydro-1H-indol-2-one [J].

Lathourakis, GE ;

Litinas, KE .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1996, (05) :491-493

[9] Enterohemorrhagic Escherichia coli biofilms are inhibited by 7-hydroxyindole and stimulated by isatin [J].

Lee, Jintae ;

Bansal, Tarun ;

Jayaraman, Arul ;

Bentley, William E. ;

Wood, Thomas K. .

APPLIED AND ENVIRONMENTAL MICROBIOLOGY, 2007, 73 (13) :4100-4109

[10] Reactions of α-diketones and o-quinones with phosphorus compounds [J].

Osman, FH ;

El-Samahy, FA .

CHEMICAL REVIEWS, 2002, 102 (03) :629-677

← 1 2 →