Cyclic aromatic systems with hypervalent centers

被引：125

作者：

Minkin, VI ^{[1
]}

Minyaev, RM ^{[1
]}

机构：

[1] Rostov State Univ, Inst Phys & Organ Chem, Rostov Na Donu 344090, Russia

来源：

CHEMICAL REVIEWS | 2001年 / 101卷 / 05期

关键词：

D O I：

10.1021/cr990358h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cyclic aromatic systems with hypervalent centers were studied. The cooperative effects of the hypervalent bonding and aromaticity in the bicyclic structures were also discussed. The results showed that the aromatic stabilization of the T-shaped hypervalent arrangement at the tricoordinate pnictogen center facilitates the rearrangement and directs it along the reaction path with the aromatic transition-state structure.

引用

页码：1247 / 1265

页数：19

共 93 条

[1]

AGRANAT I, 1973, THEORETICAL AROMATIC, V8, P140

[2]

ALBRIGHT TA, 1985, ORBITAL INTERACTIONS, P258

[3] Molecular and vibrational structure of 1,6,6a lambda(4)-trithiapentalene. Infrared linear dichroism spectroscopy and ab initio normal-mode analyses [J].

Andersen, KB ;

Abildgaard, J ;

Radziszewski, JG ;

SpangetLarsen, J .

JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (24) :4475-4480

[4] BONDING BETWEEN NONBONDED SULFUR AND OXYGEN-ATOMS IN SELECTED ORGANIC-MOLECULES (A QUANTUM CHEMICAL STUDY) [J].

ANGYAN, JG ;

POIRIER, RA ;

KUCSMAN, A ;

CSIZMADIA, IG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (08) :2237-2245

[5] LOW-COORDINATE HYPERVALENT PHOSPHORUS [J].

ARDUENGO, AJ ;

STEWART, CA .

CHEMICAL REVIEWS, 1994, 94 (05) :1215-1237

[6] CHEMISTRY OF TRICOORDINATE HYPERVALENT PNICTOGENS [J].

ARDUENGO, AJ .

PURE AND APPLIED CHEMISTRY, 1987, 59 (08) :1053-1055

[7] THE CHEMISTRY OF 10-PN-3 SYSTEMS1 - TRICOORDINATE HYPERVALENT PNICTOGEN COMPOUNDS AND RELATED SYSTEMS [J].

ARDUENGO, AJ ;

DIXON, DA ;

STEWART, CA .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1987, 30 (1-2) :341-344

[8]

ARDUENGO AJ, 1990, HETEROATOM CHEMISTRY /, P47

[9] DIRECT DETERMINATION OF THE BARRIER TO EDGE INVERSION AT TRIVALENT PHOSPHORUS - VERIFICATION OF THE EDGE INVERSION MECHANISM [J].

ARDUENGO, AJ ;

DIXON, DA ;

ROE, DC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (21) :6821-6823

[10] THE SYNTHESIS, STRUCTURE, AND CHEMISTRY OF 10-PN-3 SYSTEMS - TRICOORDINATE HYPERVALENT PNICTOGEN COMPOUNDS [J].

ARDUENGO, AJ ;

STEWART, CA ;

DAVIDSON, F ;

DIXON, DA ;

BECKER, JY ;

CULLEY, SA ;

MIZEN, MB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (03) :627-647

← 1 2 3 4 5 6 7 8 9 10 →