Studies of the deposition of CaCO3 on a stainless steel surface by a novel electrochemical technique

被引:47
作者
Morizot, A
Neville, A
Hodgkiess, T
机构
[1] Heriot Watt Univ, Dept Mech & Chem Engn, Edinburgh EH14 4AS, Midlothian, Scotland
[2] Univ Glasgow, Dept Mech Engn, Glasgow G12 8QQ, Lanark, Scotland
关键词
scale; inhibitor; carbonate; cathodic; RDE; Levich;
D O I
10.1016/S0022-0248(98)01035-5
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
This pager describes the application of a novel electrochemical-based technique for the investigation of scale deposition directly on a metallic surface. The work, also involving conventional bulk chemistry, has comprised a comparison of scale control inhibition by polyacrylic acid on bulk precipitation and on deposition at an electrode surface. It has been shown that the new technique can monitor the influence of an inhibitor on scale deposition. Moreover the new experimental approach has provided evidence that the efficiency of inhibitors may be substantially different in relation to surface deposition and bulk precipitation. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:738 / 743
页数:6
相关论文
共 10 条
[1]  
FILINISKY VY, 1976, PROGR SURFACE MEMBRA, V10
[2]   Calcium carbonate solubility: A reappraisal of scale formation and inhibition [J].
Gal, JY ;
Bollinger, JC ;
Tolosa, H ;
Gache, N .
TALANTA, 1996, 43 (09) :1497-1509
[3]  
Hasson D., 1996, DESALINATION, V108, P67
[4]  
LEVICH VG, 1942, ACTA PHYSICOCHIM URS, V17, P257
[5]  
Neville A, 1998, CORROSION 98
[6]  
NEVILLE A, 1998, IN PRESS J APPL ELEC
[8]  
SHAUGHNESSY CM, 1983, J PET TECH OCT, P1783
[9]   Carboxymethyl inulin: A new inhibitor for calcium carbonate precipitation [J].
Verraest, DL ;
Peters, JA ;
vanBekkum, H ;
vanRosmalen, GM .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1996, 73 (01) :55-62
[10]  
WALKER CK, 1994, CORROSION 94