Synthesis and crystal and molecular structure of a sterically unhindered organoindium hydride compound, [Li(tmeda)2][Me3In-H-InMe3]

被引：12

作者：

Hibbs, DE

Hursthouse, MB

Jones, C

Smithies, NA

机构：

[1] Univ Wales, Dept Chem, Swansea SA2 8PP, W Glam, Wales

[2] Univ Wales, Dept Chem, EPSRC Xray Crystallog Serv, Cardiff CF1 3TB, S Glam, Wales

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 14期

关键词：

D O I：

10.1021/om980202s

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction. of either InMe3. Et2O or InMe2Cl with a Large excess of lithium hydride affords the organoindium hydride compound, [Li(tmeda)(2)][Me3InH-InMe3], the X-ray crystal structure of which shows the anion to have a bent hydride bridge.

引用

页码：3108 / 3110

页数：3

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