Preparation of poly(styrene-block-butyl acrylate) block copolymer-silicate nanocomposites

被引：80

作者：

Zhao, HY

Shipp, DA ^{[1
]}

机构：

[1] Clarkson Univ, Dept Chem, Potsdam, NY 13699 USA

[2] Clarkson Univ, Ctr Adv Mat Proc, Potsdam, NY 13699 USA

来源：

CHEMISTRY OF MATERIALS | 2003年 / 15卷 / 14期

关键词：

D O I：

10.1021/cm034013y

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An initiator was intercalated into the interlayer spacings of montmorillonite clay, from which poly(styrene-block-butyl acrylate) silicate nanocomposites were prepared using atom transfer radical polymerization. A mixture of exfoliated structure and intercalated structure was produced in the nanocomposite. The poly(butyl acrylate) chains form microdomains with an average size of 2-5 nm.

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页码：2693 / 2695

页数：3

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