Reactivity of oxonaphtoporphyrins.: Efficient β-functionalization of the porphyrin ring on reaction with nitrogen or carbon nucleophiles

被引：33

作者：

Richeter, S ^{[1
]}

Jeandon, C ^{[1
]}

Ruppert, R ^{[1
]}

Callot, HJ ^{[1
]}

机构：

[1] Univ Strasbourg, Fac Chim, F-67000 Strasbourg, France

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 11期

关键词：

D O I：

10.1016/S0040-4039(00)02345-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Oxonaphtoporphyrins show a 1,4 reactivity involving the conjugated pyrrole double bond, the addition being followed by oxidation or elimination leading to rearomatization. Addition of nitrogen or carbon nucleophiles gives amino and substituted aminoporphyrins, or alkyl and cyanoporphyrins, respectively. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：2103 / 2106

页数：4

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