Determination of the vapor density of triacetone triperoxide (TATP) using a gas chromatography headspace technique

被引：122

作者：

Oxley, JC ^{[1
]}

Smith, JL ^{[1
]}

Shinde, K ^{[1
]}

Moran, J ^{[1
]}

机构：

[1] Univ Rhode Isl, Dept Chem, Kingston, RI 02881 USA

来源：

PROPELLANTS EXPLOSIVES PYROTECHNICS | 2005年 / 30卷 / 02期

关键词：

TATP; 1,1,4,4,7,7-hexamethyl-1,4,7-cyclononatriperoxane; TNT; 2,4,6-trinitrotoluene; vapor pressure of explosives; explosive detection;

D O I：

10.1002/prep.200400094

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Using a GC headspace measurement technique, the vapor pressure of TATP was determined over the temperature range 12 to 60 degrees C. As a check on the experimental method, TNT vapor pressure was likewise computed. Values for TNT are in excellent agreement with previous published ones. For TATP the vapor pressure was found to be similar to 7 Pa at ambient conditions. This value translates to a factor of 10(4) more molecules of TATP in air than TNT at room temperature. The dependence of TATP vapor pressure on temperature can be described by the equation log(10)P(Pa) = 19.791 - 5708/T(K). Its heat of sublimation has been calculated as 1.09 kJ/mol.

引用

页码：127 / 130

页数：4

共 24 条

[1]

Bellamy AJ, 1999, J FORENSIC SCI, V44, P603

[2] VAPOR-PRESSURE MEASUREMENTS ON SOME ORGANIC HIGH EXPLOSIVES [J].

CUNDALL, RB ;

PALMER, TF ;

WOOD, CEC .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1978, 74 :1339-1345

[3]

Dionne B.C., 1986, Journal of Energetic Materials, V4, P447, DOI DOI 10.1080/07370658608011353

[4]

Dobratz B. M., 1985, EXPLOSIVES HDB PRINC

[5] THE VAPOUR PRESSURE OF 2-4-6-TRINITROTOLUENE [J].

EDWARDS, G .

TRANSACTIONS OF THE FARADAY SOCIETY, 1950, 46 (4-5) :423-427

[6]

EVANS HK, 1986, J FORENSIC SCI, V31, P1119

[7]

Gibbs T.R., 1980, LOS ALAMOS SCI LAB E

[8]

HON DNS, 1985, PULP PAP-CANADA, V86, P129

[9]

Kaye SM, 1978, ENCY EXPLOSIVES RELA, V8, P203

[10] VAPOR-PRESSURE OF 2,4,6-TRINITROTOLUENE BY A GAS-CHROMATOGRAPHIC HEADSPACE TECHNIQUE [J].

LEGGETT, DC .

JOURNAL OF CHROMATOGRAPHY, 1977, 133 (01) :83-90

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