Polymerization of hex-1-ene by homogeneous zirconocene and hafnocene catalysts in compressed solution

被引：18

作者：

Fries, A ^{[1
]}

Mise, T ^{[1
]}

Matsumoto, A ^{[1
]}

Ohmori, H ^{[1
]}

Wakatsuki, Y ^{[1
]}

机构：

[1] INST PHYS & CHEM RES,WAKO,SAITAMA 35101,JAPAN

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 06期

关键词：

D O I：

10.1039/cc9960000783

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Poly(hexene) with very high molecular weight is produced at 250 MPa (2500 atm) with (C(5)HMe(4))(2)HfCl2-methyl aluminoxane (MAO) as catalyst; the dependence of the polymerization on the reaction pressure (0.1 MPa-1.5 GPa) and the substituent pattern of a zirconocene catalyst is described.

引用

收藏

页码：783 / 784

页数：2

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