Fluorinated Ethylene Carbonate as Electrolyte Additive for Rechargeable Na Batteries

被引：624

作者：

Komaba, Shinichi ^{[1
]}

Ishikawa, Toru ^{[1
]}

Yabuuchi, Naoaki ^{[1
]}

Murata, Wataru ^{[1
]}

Ito, Atsushi ^{[2
]}

Ohsawa, Yasuhiko ^{[2
]}

机构：

[1] Tokyo Univ Sci, Dept Appl Chem, Shinjuku Ku, Tokyo 1628601, Japan

[2] Nissan Motor Co Ltd, Nissan Res Ctr, Yokosuka, Kanagawa 2378523, Japan

来源：

ACS APPLIED MATERIALS & INTERFACES | 2011年 / 3卷 / 11期

关键词：

Na-ion battery; sodium insertion; sodium electrodeposition; electrochemistry; ELECTROCHEMICAL INSERTION; FLUOROETHYLENE CARBONATE; ALKYL CARBONATE; LITHIUM; INTERPHASE; SODIUM; LI; IDENTIFICATION; GRAPHITE; SURFACE;

D O I：

10.1021/am200973k

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Fluoroethylene carbonate is an efficient electrolyte additive to improve the reversibility of electrochemical sodium insertion for hard-carbon and NaNi1/2Mn1/2O2 electrodes in aprotic Na cells. The additive is also capable of the electrochemical deposition/dissolution of metallic Na with higher reversibility because of improved passivation and suppression of side reactions between Na metal and propylene carbonate solution containing Na salts.

引用

页码：4165 / 4168

页数：4

共 24 条

[1] Carbon black:: a promising electrode material for sodium-ion batteries [J].

Alcántara, R ;

Jiménez-Mateos, JM ;

Lavela, P ;

Tirado, JL .

ELECTROCHEMISTRY COMMUNICATIONS, 2001, 3 (11) :639-642

[2] IDENTIFICATION OF SURFACE-FILMS FORMED ON LITHIUM IN PROPYLENE CARBONATE SOLUTIONS [J].

AURBACH, D ;

DAROUX, ML ;

FAGUY, PW ;

YEAGER, E .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (07) :1611-1620

[3] A sodium-ion cell based on the fluorophosphate compound NaVPO4F [J].

Barker, J ;

Saidi, MY ;

Swoyer, JL .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2003, 6 (01) :A1-A4

[4]

Berthelot R, 2011, NAT MATER, V10, P74, DOI [10.1038/nmat2920, 10.1038/NMAT2920]

[5] ELECTROCHEMICAL INSERTION OF SODIUM INTO CARBON [J].

DOEFF, MM ;

MA, YP ;

VISCO, SJ ;

DEJONGHE, LC .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1993, 140 (12) :L169-L170

[6] Identification of Li battery electrolyte degradation products through direct synthesis and characterization of alkyl carbonate salts [J].

Gireaud, L ;

Grugeon, S ;

Laruelle, S ;

Pilard, S ;

Tarascon, JM .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (05) :A850-A857

[7] Physical properties of substituted 1,3-dioxolan-2-ones [J].

Hagiyama, Kousuke ;

Suzuki, Keita ;

Ohtake, Manabu ;

Shimada, Miki ;

Nanbu, Noritoshi ;

Takehara, Masahiro ;

Ue, Makoto ;

Sasaki, Yukio .

CHEMISTRY LETTERS, 2008, 37 (02) :210-211

[8]

Jehoulet C., 1997, EL SOC INT SOC EL M, V97-2, P153

[9] Development of direct fluorination technology for application to materials for lithium battery [J].

Kobayashi, M ;

Inoguchi, T ;

Iida, T ;

Tanioka, T ;

Kumase, H ;

Fukai, Y .

JOURNAL OF FLUORINE CHEMISTRY, 2003, 120 (02) :105-110

[10] Impact of 2-vinylpyridine as electrolyte additive on surface and electrochemistry of graphite for C/LiMn2O4 Li-ion cells [J].

Komaba, S ;

Itabashi, T ;

Ohtsuka, T ;

Groult, H ;

Kumagai, N ;

Kaplan, B ;

Yashiro, H .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (05) :A937-A946

← 1 2 3 →