Microwave-accelerated asymmetric allylations using cysteine derived oxazolidine and thiazolidine palladium complexes

被引：30

作者：

Braga, AL ^{[1
]}

Silveira, CC

de Bolster, MWG

Schrekker, HS

Wessjohann, LA

Schneider, PH

机构：

[1] Univ Fed Santa Maria, Dept Quim, BR-97105900 Santa Maria, RS, Brazil

[2] Free Univ Amsterdam, Dept Organ & Inorgan Chem, Fac Sci, Div Chem, NL-1081 HV Amsterdam, Netherlands

[3] Leibniz Inst Plant Biochem, D-06120 Halle An Der Saale, Germany

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2005年 / 239卷 / 1-2期

关键词：

microwave; palladium; allylation; asymmetric catalysis; oxazolidine; thiazolidine;

D O I：

10.1016/j.molcata.2005.06.008

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A set of enantiopure oxazolidine-thioether and thiazolidine-alcohol palladium complexes catalyze the microwave-mediated enantioselective allylation of rac-1,3-diphenyl-2-propenyl acetate with dimethyl malonate. Good yields and ee's were achieved in reaction times of 2 min instead of hours with conventional heating. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：235 / 238

页数：4

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