Sub-10 fs excited state evolution in polycarbazolyldiacetylene-polyethylene blends

被引:11
作者
Cerullo, G [1 ]
Lanzani, G
Zavelani-Rossi, M
De Silvestri, S
Comoretto, D
Moggio, I
Dellepiane, G
机构
[1] Ist Nazl Fis Mat, Milan, Italy
[2] Politecn Milan, Dipartimento Fis, I-20133 Milan, Italy
[3] Univ Genoa, Dipartimento Chim & Chim Ind, I-16146 Genoa, Italy
关键词
time resolved spectroscopy; photoinduced absorption; Raman spectroscopy;
D O I
10.1016/S0379-6779(00)00515-4
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We report on sub-10 femtosecond time-resolved optical dynamics in polycarbazolyldiacetylene blended in a polyethylene matrix which is a prototype of single chain systems. Transmission difference data reveal an ultrafast kinetics which is assigned to the rapid internal conversion taking place following photoexcitation. Oscillations in the time-dependent traces are assigned to impulsive stimulated resonant Raman scattering, based on the comparison with cw Raman data. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:57 / 60
页数:4
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