Comments on the thermodynamics of solid electrodes

被引：82

作者：

Lipkowski, J ^{[1
]}

Schmickler, W

Kolb, DM

Parsons, R

机构：

[1] Univ Guelph, Dept Chem & Biochem, Guelph, ON N1G 2W1, Canada

[2] Univ Ulm, Abt Electrochem, D-89069 Ulm, Germany

[3] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1998年 / 452卷 / 02期

关键词：

surface stress; interfacial tension; Lippmann equation;

D O I：

10.1016/S0022-0728(98)00136-3

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The thermodynamics of solid electrodes are discussed in light of the recent measurements of surface stress. Interfacial tension and surface stress are not even approximately equal, and they generally exhibit a different dependence on the electrode potential. The variation of the interfacial strain with potential is small so that the Lippmann equation for a solid is practically the same as for a liquid electrode. Changes in the interfacial tension can be obtained by integrating the charge density over the potential. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：193 / 197

页数：5

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