Microstructure and elastic modulus of ceramic Li x Na1-x NbO3 perovskite solid solutions prepared at 6 GPa

被引:2
作者
Palatnikov, M. N. [1 ]
Shcherbina, O. B. [1 ]
Efremov, V. V. [1 ]
Sidorov, N. V. [1 ]
Salak, A. N. [2 ]
机构
[1] Russian Acad Sci, Kola Sci Ctr, Tananaev Inst Chem & Technol Rare Elements & Mine, Apatity 184209, Murmansk Oblast, Russia
[2] Univ Aveiro, Dept Ceram & Glass Engn CICECO, P-3810193 Aveiro, Portugal
基金
俄罗斯基础研究基金会;
关键词
Ceramic materials - Elastic moduli - Lithium compounds - Microstructure - Niobium compounds - Perovskite - Sintering - Sodium compounds;
D O I
10.1134/S0020168510120149
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The microstructure of ceramic samples of high-pressure ferroelectric Li (x) Na1 - x NbO3 (x = 0.17, 0.25) perovskite solid solutions has been studied in relation to synthesis temperature and composition. The elastic properties (Young's modulus) of the high-pressure Li (x) Na1 - x NbO3 (x = 0.125, 0.17, 0.25) solid solutions have been studied for the first time by a contact technique. The results demonstrate that, with increasing sintering temperature, the Young's modulus of the high-pressure Li (x) Na1 - x NbO3 solid solutions at singular concentration points (x (i) = 0.125 and 0.25, Li/Na = 1/7 and 1/3) increases considerably, whereas that of Li0.17Na0.83NbO3 decreases markedly, which seems to be related to the recrystallization behavior of ordered and disordered solid solutions at high pressures.
引用
收藏
页码:1348 / 1352
页数:5
相关论文
共 8 条
[1]  
Gogolinskii K.V., 1998, ZAVODSK LAB, V64, P30
[2]   HOT-PRESSING OF SODIUM LITHIUM-NIOBATE CERAMICS WITH PEROVSKITE-TYPE STRUCTURES [J].
HARDIMAN, B ;
HENSON, RM ;
REEVES, CP ;
ZEYFANG, RR .
FERROELECTRICS, 1976, 12 (1-4) :157-159
[3]   Comparative Acoustic and Contact Studies of Elasticity of Ferroelectric LixNa1-xTa0.1Nb0.9O3 Solid Solutions at Nanometer Spatial Resolution [J].
Palatnikov, M. ;
Efremov, V. ;
Makarova, O. ;
Bormanis, K. .
FERROELECTRICS, 2009, 378 :31-36
[4]  
PALATNIKOV MN, 2002, SEGNETOELEKTRICHESKI, P303
[5]  
PALATNIKOV MN, 2008, IAN SSSR NEORG MATER, V44, P1375
[6]  
PUSHKAREV AV, 2003, MEZHD NAUCHN K AKT P, P163
[7]  
RADYUSH YV, 2003, SBORN T MEZHD S POR, P233
[8]  
VENEVTSEV YN, 1965, SEGNETO ANTISEGNETOE, P255