Synthesis, characterization, and molecular structure of bis{(tert-butyldimethylsilyl)-tetramethylcyclopentadienyl}lead

被引:19
作者
Constantine, SP [1 ]
Hitchcock, PB [1 ]
Lawless, GA [1 ]
机构
[1] UNIV SUSSEX,SCH CHEM & MOL SCI,BRIGHTON,E SUSSEX,ENGLAND
关键词
D O I
10.1021/om960511n
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reaction of 2 equiv of LiCp(s)[Cp(s) = C(5)Me(4)(SiMe(2)Bu(t))] with PbCl2 affords the corresponding metallocene, [Pb(eta(5)-Cp(s))(2)] in high yield. A single-crystal X-ray analysis reveals the planar cyclopentadienyl rings to be parallel.
引用
收藏
页码:3905 / 3906
页数:2
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