Copper(II) compounds of some Mannich-condensation amine-bis-imidazole ligands

被引：9

作者：

Driessen, WL

Rehorst, D

Reedijk, J

Mutikainen, P

Turpeinen, U

机构：

[1] Leiden Inst Chem, Gorlaeus Labs, NL-2300 RA Leiden, Netherlands

[2] Univ Helsinki, Dept Chem, SF-00100 Helsinki 10, Finland

来源：

INORGANICA CHIMICA ACTA | 2003年 / 355卷

关键词：

formaldehyde; amines; imidazole; condensation; copper;

D O I：

10.1016/S0020-1693(03)00224-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Mannich condensation of formaldehyde with some amines and imidazoles rendered four bis-imidazole ligands in a very simple one pot reaction. The X-ray structures of four copper(II) compounds, obtained with these ligands, show in all cases the copper(II) ions to be in a square pyramidal environment. Three compounds appeared to be mononuclear, while the least bulky ligand rendered a dinuclear complex. (C) 2003 Elsevier B.V. All rights reserved.

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页码：64 / 68

页数：5

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