Chiral ferrocenes as novel rotary modules for molecular machines

被引:52
作者
Kinbara, Kazushi [1 ]
Muraoka, Takahiro
Aida, Takuzo
机构
[1] Univ Tokyo, Dept Chem & Biotechnol, Bunkyo Ku, Tokyo 1138656, Japan
关键词
D O I
10.1039/b718982f
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Ferrocene, a double-decker organometallic compound that generates angular motion, can be used as a unique rotary module for molecular machines. By interlocking a ferrocene-based rotary module with a photochromic unit, we have developed novel molecular machines that operate via power-conversion mechanisms. This design strategy, which mimics real machines in our daily life, allows for remote control of molecular events.
引用
收藏
页码:1871 / 1876
页数:6
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