Waterlike dynamic anomalies in a liquid described by a core-softened potential

被引:17
作者
Egorov, S. A. [1 ]
机构
[1] Univ Virginia, Dept Chem, Charlottesville, VA 22901 USA
关键词
D O I
10.1063/1.2917359
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We present a theoretical study of transport properties of a liquid comprised of particles interacting via isotropic core-softened potential. Shear viscosity and self-diffusion coefficient are computed on the basis of the mode-coupling theory, with required structural input obtained from thermodynamically self-consistent integral equation theory. Both self-diffusion coefficient and viscosity display waterlike anomalous density dependence, with diffusivity increasing and viscosity decreasing with density within a particular density range along several isotherms below a certain temperature. Our theoretical results for both transport coefficients are in good agreement with the simulation data.(c) 2008 American Institute of Physics.
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页数:6
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