Photoinduced desorption of molecules from metal surfaces using femtosecond pulses: A model dynamical study

被引：13

作者：

Chakrabarti, N

Sathyamurthy, N

Gadzuk, JW ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India

[2] NIST, Gaithersburg, MD 20899 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 1998年 / 102卷 / 23期

关键词：

D O I：

10.1021/jp980043q

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The influence of a femtosecond laser pulse on an adsorbate molecule-metal surface system is investigated by considering a time-dependent coupling between the ground-and excited-state potential energy curves using the time-dependent quantum mechanical wave packet approach. It is shown that the probability of desorption is strongly dependent on the duration of the coupling and the image-charge attraction and that it increases with increase in vibrational excitation of the metal-adsorbate bond.

引用

收藏

页码：4154 / 4157

页数：4

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