Role of lattice strain and defects in copper particles on the activity of Cu/ZnO/Al2O3 catalysts for methanol synthesis

被引：222

作者：

Kasatkin, Igor

Kurr, Patrick

Kniep, Benjamin

Trunschke, Annette

Schloegl, Robert

机构：

[1] Max Planck Soc, Fritz Haber Inst, D-14195 Berlin, Germany

[2] R&D Catalysis, Sud Chem AG, D-33052 Bruckmuhl, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 38期

关键词：

aluminum; copper; electron microscopy; methanol synthesis; zinc;

D O I：

10.1002/anie.200702600

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) On the nature of copper in real methanol synthesis catalysts: Cu/Zn/Al2O3 catalysts with industrially relevant high copper content have been investigated. With the aid of combined TEM (see picture) and XRD analysis, imperfections in the Cu lattice arising from twinning, fault defects, and strain are found to be related to increased activity of the catalysts in methanol synthesis. © 2007 Wiley-VCH Verlag GmbH S. Co. KGaA.

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页码：7324 / 7327

页数：4

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