Improvement of corrosion resistance of magnesium metal by rare earth elements

Mg metal containing rare earth metals (REs) can be electrowon directly by molten salt electrolysis. The clarification of the optimum RE content in Mg is necessary to fix the electrolytic conditions in the direct electrowinning of Mg with RE. From this point of view, effect of RE addition in Mg metal on its corrosion property was studied in detail in this study. The specimen was prepared by adding La, Nd, or Cc in melted Mg metal, and its corrosion resistance was examined by an immersion test in 3 mass%-NaCl solution at room temperature. The corrosion resistance of Mg was improved greatly by adding a small amount of RE, whereas the excess addition of RE deteriorated the corrosion resistance. The optimum RE content was about 0.5 mass%. In this study, the corrosion property of Mg with an artificial surface oxide layer was also studied to clarify the effect of surface oxide. The corrosion resistance of Mg was particularly strengthened by conversion coating in a solution including La(NO3)(3), Nd(NO3)(3), or Ce(NO3)(3), with Mg(NO3)(2). This result suggests that the surface oxide film consisting of both Mg and RE gives ideal corrosion resistance to Mg metal. Mg metal with conversion coating including RE should also be of use as a corrosion-resistant material. (C) 2007 Elsevier Ltd. All rights reserved.