Rate-determining electron-transfer reactions in highly aqueous alcohol-water mixtures. A quantitative analysis of solvent effects on the oxidation of 4-methoxyphenylacetate by potassium 12-tungstocobaltate(III)

被引：8

作者：

Bietti, M

Baciocchi, E

Engberts, JBFN

机构：

[1] UNIV ROMA LA SAPIENZA,DIPARTIMENTO CHIM,I-00185 ROME,ITALY

[2] UNIV GRONINGEN,DEPT ORGAN & MOL INORGAN CHEM,9747 AG GRONINGEN,NETHERLANDS

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 11期

关键词：

D O I：

10.1039/cc9960001307

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Kinetic solvent effects on the rate-determining outer-sphere electron-transfer reaction between 4-methoxy-phenylacetate and potassium 12-tungstocobaltate(III) in highly aqueous alcohol-water mixtures are quantitatively analysed in terms of pairwise Gibbs energy parameters for interaction of the initial and transition state with the cosolvent.

引用

收藏

页码：1307 / 1308

页数：2

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