The presence of amoxicillin, a widely used antibiotic, has been documented in Sewage Treatment Plant (STP) effluents. As for other pharmaceuticals, ozonation is proposed as a process for its abatement from these effluents. The results of ozonation experiments on amoxicillin containing aqueous solutions indicate that ozone attack is mainly directed towards the phenolic ring of the studied molecule leading to the formation of hydroxyderivative intermediates. No direct evidences of attack on sulfur atom with sulfoxide formation are found. A kinetic investigation is carried out allowing the assessment of the kinetics of direct ozone attack and that of OH radicals to amoxicillin. (c) 2005 Elsevier B.V. All rights reserved.
机构:
Univ Naples Federico II, Fac Ingn, Dipartimento Ingn Chim, I-80125 Naples, ItalyUniv Naples Federico II, Fac Ingn, Dipartimento Ingn Chim, I-80125 Naples, Italy
Caprio, V
;
Marotta, R
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Univ Naples Federico II, Fac Ingn, Dipartimento Ingn Chim, I-80125 Naples, ItalyUniv Naples Federico II, Fac Ingn, Dipartimento Ingn Chim, I-80125 Naples, Italy
Marotta, R
;
Radovnikovic, A
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Univ Naples Federico II, Fac Ingn, Dipartimento Ingn Chim, I-80125 Naples, ItalyUniv Naples Federico II, Fac Ingn, Dipartimento Ingn Chim, I-80125 Naples, Italy
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Univ New S Wales, Sch Civil & Environm Engn, CRC Water Qual & Treatment, Sydney, NSW 2052, AustraliaUniv New S Wales, Sch Civil & Environm Engn, CRC Water Qual & Treatment, Sydney, NSW 2052, Australia
机构:
Univ Naples Federico II, Fac Ingn, Dipartimento Ingn Chim, I-80125 Naples, ItalyUniv Naples Federico II, Fac Ingn, Dipartimento Ingn Chim, I-80125 Naples, Italy
Caprio, V
;
Marotta, R
论文数: 0引用数: 0
h-index: 0
机构:
Univ Naples Federico II, Fac Ingn, Dipartimento Ingn Chim, I-80125 Naples, ItalyUniv Naples Federico II, Fac Ingn, Dipartimento Ingn Chim, I-80125 Naples, Italy
Marotta, R
;
Radovnikovic, A
论文数: 0引用数: 0
h-index: 0
机构:
Univ Naples Federico II, Fac Ingn, Dipartimento Ingn Chim, I-80125 Naples, ItalyUniv Naples Federico II, Fac Ingn, Dipartimento Ingn Chim, I-80125 Naples, Italy
机构:
Univ New S Wales, Sch Civil & Environm Engn, CRC Water Qual & Treatment, Sydney, NSW 2052, AustraliaUniv New S Wales, Sch Civil & Environm Engn, CRC Water Qual & Treatment, Sydney, NSW 2052, Australia