Antibiotic removal from wastewaters: The ozonation of amoxicillin

被引:352
作者
Andreozzi, R
Canterino, M
Marotta, R
Paxeus, N
机构
[1] Univ Naples Federico II, Fac Ingn, Dipartimento Ingn Chim, I-80125 Naples, Italy
[2] Gryaab Goteborg Reg Sewage Works, S-41834 Gothenburg, Sweden
关键词
amoxicillin; Sewage Treatment Plant effluents; ozonation experiments;
D O I
10.1016/j.jhazmat.2005.03.004
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The presence of amoxicillin, a widely used antibiotic, has been documented in Sewage Treatment Plant (STP) effluents. As for other pharmaceuticals, ozonation is proposed as a process for its abatement from these effluents. The results of ozonation experiments on amoxicillin containing aqueous solutions indicate that ozone attack is mainly directed towards the phenolic ring of the studied molecule leading to the formation of hydroxyderivative intermediates. No direct evidences of attack on sulfur atom with sulfoxide formation are found. A kinetic investigation is carried out allowing the assessment of the kinetics of direct ozone attack and that of OH radicals to amoxicillin. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:243 / 250
页数:8
相关论文
共 43 条
[1]   Paracetamol oxidation from aqueous solutions by means of ozonation and H2O2/UV system [J].
Andreozzi, R ;
Caprio, V ;
Marotta, R ;
Vogna, D .
WATER RESEARCH, 2003, 37 (05) :993-1004
[2]   Ozonation and H2O2/UV treatment of clofibric acid in water:: a kinetic investigation [J].
Andreozzi, R ;
Caprio, V ;
Marotta, R ;
Radovnikovic, A .
JOURNAL OF HAZARDOUS MATERIALS, 2003, 103 (03) :233-246
[3]   Measuring ozonation rate constants in gas-liquid reactors under the kinetic-diffusional transition regime [J].
Andreozzi, R ;
Caprio, V ;
Insola, A ;
Tufano, V .
CHEMICAL ENGINEERING COMMUNICATIONS, 1996, 143 :195-204
[4]   Antibiotics in the environment:: Occurrence in Italian STPs, fate, and preliminary assessment on algal toxicity of amoxicillin [J].
Andreozzi, R ;
Caprio, V ;
Ciniglia, C ;
De Champdoré, M ;
Lo Giudice, R ;
Marotta, R ;
Zuccato, E .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2004, 38 (24) :6832-6838
[5]   Advanced oxidation processes for the treatment of mineral oil-contaminated wastewaters [J].
Andreozzi, R ;
Caprio, V ;
Insola, A ;
Marotta, R ;
Sanchirico, R .
WATER RESEARCH, 2000, 34 (02) :620-628
[6]  
[Anonymous], 1983, ENG OPTIMIZATION
[7]   Pre-treatment of penicillin formulation effluent by advanced oxidation processes [J].
Arslan-Alaton, I ;
Dogruel, S .
JOURNAL OF HAZARDOUS MATERIALS, 2004, 112 (1-2) :105-113
[8]   Risk analysis of drinking water microbial contamination versus disinfection by-products (DBPs) [J].
Ashbolt, NJ .
TOXICOLOGY, 2004, 198 (1-3) :255-262
[9]   Treatment of pharmaceutical wastewater containing antibiotics by O3 and O3/H2O2 processes [J].
Balcioglu, IA ;
Ötker, M .
CHEMOSPHERE, 2003, 50 (01) :85-95
[10]   Kinetics of the reaction between ozone and phenolic acids present in agro-industrial wastewaters [J].
Beltran-Heredia, J ;
Torregrosa, J ;
Dominguez, JR ;
Peres, JA .
WATER RESEARCH, 2001, 35 (04) :1077-1085