Benzo[f]- and Benzo[h]Coumarin-Containing poly(methyl methacrylate)s and poly(methyl methacrylate)s with pendant coumarin-containing azo dyes

被引：31

作者：

Abd-El-Aziz, Alaa S. ^{[1
,2
]}

Shipman, Patrick O. ^{[1
,2
]}

Neeland, Edward G. ^{[1
]}

Corkery, T. Christopher ^{[2
]}

Mohammed, Shawkat ^{[1
,3
]}

Harvey, Pierre D. ^{[3
]}

Mohamed, Hany M. ^{[2
]}

Bedair, Ahmed H. ^{[2
]}

El-Agrody, Ahmed M. ^{[2
]}

Aguiar, Pedro M. ^{[2
]}

Kroeker, Scott ^{[2
]}

机构：

[1] Univ British Columbia Okanagan, Dept Chem, Kelowna, BC, Canada

[2] Univ Winnipeg, Dept Chem, Winnipeg, MB R3B 2E9, Canada

[3] Univ Sherbrooke, Dept Chim, Sherbrooke, PQ J1K 2R1, Canada

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 2008年 / 209卷 / 01期

关键词：

D O I：

10.1002/macp.200700476

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 [高分子化学与物理]; 080501 [材料物理与化学]; 081704 [应用化学];

摘要：

A series of coumarins were reacted with methacrylate or styrene derivatives to form new olefinic coumarin monomers that were polymerized using 2,2'-azoisobutyronitrile (AIBN). These polymers were highly insoluble in organic solvents and displayed good thermal stability with glass-transition temperatures between 70 degrees C and 130 degrees C. Luminescence studies on some of the coumarin-containing polymers (CCPs) showed some fluorescence (Phi(F) around 0.1). Some of the newly-prepared coumarins and benzocoumarins were reacted with azo dyes to form mixed coumarin-azo dye complexes. These mixed complexes were further reacted to prepare acrylic monomers and polymerized using AIBN. These polymers were thermally stable and poorly soluble in organic solvents.

引用

页码：84 / 103

页数：20

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