Cross dipole stacking in the crystal of distyrylbenzene derivative: The approach toward high solid-state luminescence efficiency

被引:348
作者
Xie, ZQ
Yang, B
Li, F
Cheng, G
Liu, LL
Yang, GD
Xu, H
Ye, L
Hanif, M
Liu, SY
Ma, DG
Ma, YG [1 ]
机构
[1] Jilin Univ, Key Lab Supramol Struct & Mat, Minist Educ, Changchun 130012, Peoples R China
[2] Jilin Univ, State Key Lab Integrated Optoelect, Changchun 130012, Peoples R China
[3] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
关键词
D O I
10.1021/ja054661d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Through adding two substituent phenyl groups on distyrylbenzene, we have obtained the cross stacking of 2,5-diphenyl-1,4-distyrylbenzene with two trans double bonds (trans-DPDSB) in crystalline state. In such a cross-stacking mode, the solid-state emission exhibits high-intensity, having characteristics similar to its single molecule. The organic light-emiiting diodes (OLEDs) with attractive performance have been achieved using trans-DPDSB as a light-emitting layer, and the amplified spontaneous emission of the needlelike crystals has been observed. Copyright © 2005 American Chemical Society.
引用
收藏
页码:14152 / 14153
页数:2
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