Preparation, microstructure and properties of polyethylene aluminum nanocomposite dielectrics

被引:48
作者
Huang, Xingyi [1 ,2 ]
Jiang, Pingkai [1 ,2 ]
Kim, Chonung [1 ,2 ,3 ]
Ke, Qingquan [1 ,2 ]
Wang, Genlin [1 ,2 ]
机构
[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China
[2] Shanghai Key Lab Elect Insulat & Thermal Aging, Shanghai 200240, Peoples R China
[3] Kim Chaek Univ Technol, Fac Elect Engn, Pyongyang, North Korea
基金
中国国家自然科学基金;
关键词
polymer-matrix composites (PMCs); electrical properties; mechanical properties; microstructure;
D O I
10.1016/j.compscitech.2008.03.009
中图分类号
TB33 [复合材料];
学科分类号
摘要
Linear low density polyethylene (PE) aluminum (Al) nanocomposites were prepared and their morphology and properties were investigated. The particular attention was given to the structure/property relationship of the nanocomposites and an equivalent electric circuit model was proposed to interpret the dependences of the dielectric behaviors of the PE/Al nanocomposites on the nanoparticle concentration and the measuring frequency. The increase of the dielectric constant shows the effectiveness of Al nanoparticles in altering the intrinsic dielectric properties of PE. The microstructure transition revealed by morphological investigations has been also verified at the same composition as that from the theological data. And also, it has been found that the nanocomposites at high filler concentrations still keep good mechanical properties and breakdown strength, which is very important for practical applications. (c) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2134 / 2140
页数:7
相关论文
共 19 条
[1]   Dielectric properties of composites of multi-walled carbon nanotubes in a resin matrix [J].
Allaoui, A ;
Bai, JB ;
Rieux, N .
POLYMERS & POLYMER COMPOSITES, 2003, 11 (03) :171-178
[2]  
Barlow A., 1991, IEEE Electrical Insulation Magazine, V7, P8, DOI 10.1109/57.64966
[3]   THEORY OF DIELECTRIC-BREAKDOWN IN METAL-LOADED DIELECTRICS [J].
BEALE, PD ;
DUXBURY, PM .
PHYSICAL REVIEW B, 1988, 37 (06) :2785-2791
[4]  
Cherney EA, 2005, IEEE T DIELECT EL IN, V12, P1108, DOI 10.1109/TDEI.2005.1561790
[5]   Study on epoxy/BaTiO3 composite embedded capacitor films (ECFs) for organic substrate applications [J].
Cho, SD ;
Lee, JY ;
Hyun, JG ;
Paik, KW .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2004, 110 (03) :233-239
[6]   Conduction and polarization mechanisms and trends in dielectrics [J].
Dalkin, T. W. .
IEEE ELECTRICAL INSULATION MAGAZINE, 2006, 22 (05) :11-28
[7]   Electrical properties of polyethylene/aluminum nanocomposites [J].
Huang, X. Y. ;
Jiang, P. K. ;
Kim, C. U. .
JOURNAL OF APPLIED PHYSICS, 2007, 102 (12)
[8]   GRAIN-SIZE EFFECTS ON DIELECTRIC PROPERTIES IN BARIUM-TITANATE CERAMICS [J].
KINOSHITA, K ;
YAMAJI, A .
JOURNAL OF APPLIED PHYSICS, 1976, 47 (01) :371-373
[9]   Rheology of end-tethered polymer layered silicate nanocomposites [J].
Krishnamoorti, R ;
Giannelis, EP .
MACROMOLECULES, 1997, 30 (14) :4097-4102
[10]   Polyethylene multiwalled carbon nanotube composites [J].
McNally, T ;
Pötschke, P ;
Halley, P ;
Murphy, M ;
Martin, D ;
Bell, SEJ ;
Brennan, GP ;
Bein, D ;
Lemoine, P ;
Quinn, JP .
POLYMER, 2005, 46 (19) :8222-8232