X-ray photoelectron spectroscopy evidence for the covalent bond between an iron surface and aryl groups attached by the electrochemical reduction of diazonium salts

被引：151

作者：

Boukerma, K

Chehimi, MM

Pinson, J

Blomfield, C

机构：

[1] Univ Paris 07, ITODYS, CNRS, UMR 7086, F-75005 Paris, France

[2] Univ Paris 07, CNRS, UMR 7591, Lab Electrochim Mol, F-75251 Paris 05, France

[3] Kratos Analyt Ltd, Manchester M17 1GP, Lancs, England

来源：

LANGMUIR | 2003年 / 19卷 / 15期

关键词：

D O I：

10.1021/la030046g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The surface composition of an iron surface, after treatment by 4-carboxybenzene diazonium tetrafluoroborate (BF4- +N2C6H4COOH) was investigated. The angle-resolved x-ray photoelectron spectroscopy (XPS) was performed to probe the interfacial species formed between the diazonium salt and the iron surface. The existence of a covalent bond between an aryl group and metallic substrate (iron) by using XPS as a sensitive surface analytical tool was also discussed.

引用

页码：6333 / 6335

页数：3

共 18 条

[1] Attachment of polymers to organic moieties covalently bonded to iron surfaces
Adenier, A
Cabet-Deliry, E
Lalot, T
Pinson, J
Podvorica, F
[J]. CHEMISTRY OF MATERIALS, 2002, 14 (11) : 4576 - 4585
[2] Covalent modification of iron surfaces by electrochemical reduction of aryldiazonium salts
Adenier, A
Bernard, MC
Chehimi, MM
Cabet-Deliry, E
Desbat, B
Fagebaume, O
Pinson, J
Podvorica, F
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (19) : 4541 - 4549
[3] Covalent modification of carbon surfaces by aryl radicals generated from the electrochemical reduction of diazonium salts
Allongue, P
Delamar, M
Desbat, B
Fagebaume, O
Hitmi, R
Pinson, J
Saveant, JM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (01) : 201 - 207
[4] Organic monolayers on Si(111) by electrochemical method
Allongue, P
de Villeneuve, CH
Pinson, J
Ozanam, F
Chazalviel, JN
Wallart, X
[J]. ELECTROCHIMICA ACTA, 1998, 43 (19-20) : 2791 - 2798
[5] IMMOBILIZATION OF GLUCOSE-OXIDASE ON A CARBON SURFACE DERIVATIZED BY ELECTROCHEMICAL REDUCTION OF DIAZONIUM SALTS
BOURDILLON, C
DELAMAR, M
DEMAILLE, C
HITMI, R
MOIROUX, J
PINSON, J
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1992, 336 (1-2): : 113 - 123
[6] BOWDEN FL, 1978, ORGANIC CHEM IRON, V1, P345
[7] The electrochemical reduction of diazonium salts on iron electrodes.: The formation of covalently bonded organic layers and their effect on corrosion
Chaussé, A
Chehimi, MM
Karsi, N
Pinson, J
Podvorica, F
Vautrin-Ul, C
[J]. CHEMISTRY OF MATERIALS, 2002, 14 (01) : 392 - 400
[8] Modification of carbon fiber surfaces by electrochemical reduction of aryl diazonium salts: Application to carbon epoxy composites
Delamar, M
Desarmot, G
Fagebaume, O
Hitmi, R
Pinson, J
Saveant, JM
[J]. CARBON, 1997, 35 (06) : 801 - 807
[9] COVALENT MODIFICATION OF CARBON SURFACES BY GRAFTING OF FUNCTIONALIZED ARYL RADICALS PRODUCED FROM ELECTROCHEMICAL REDUCTION OF DIAZONIUM SALTS
DELAMAR, M
HITMI, R
PINSON, J
SAVEANT, JM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (14) : 5883 - 5884
[10] Electrochemical formation of close-packed phenyl layers on Si(111)
deVilleneuve, CH
Pinson, J
Bernard, MC
Allongue, P
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (14): : 2415 - 2420

← 1 2 →