Effect of diamagnetic cobalt on the exchange interactions in the layered lithium iron oxide

被引:2
作者
Chappel, E
Holzapfel, M
Chouteau, G
Ott, A
机构
[1] Max Planck Inst Festkorperforsch, Grenoble High Magnet Field Lab, CNRS, F-38042 Grenoble 9, France
[2] Ecole Natl Super Electrochim & Electrome Grenoble, Lab Electrochim & Physicochim Mat & Interfaces, INPG, F-38402 St Martin Dheres, France
[3] Univ Tubingen, Inst Anorgan Chem, D-72070 Tubingen, Germany
关键词
layered Heisenberg systems; metamagnetism; mean-field approximation; high-field magnetism;
D O I
10.1016/S0304-8853(00)00728-9
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Layered LiFeO2 is an antiferromagnet with a Neel temperature T-N = 20 K. Substituting Fe with diamagnetic Co3+ surprisingly leads first (up to x = 0.4). to an increase of the Weiss temperature theta and then above x = 0.4 to a decrease due to a dilution effect. Magnetic properties are qualitatively interpreted within a mean field model. with ferromagnetic layers coupled antiferromagnetically. Estimation is given of the ferro- and antiferromagnetic interactions. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:652 / 654
页数:3
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