Synthesis and characterization of polymer/clay nanocomposites by intercalated chain transfer agent

被引：90

作者：

Akat, Hakan ^{[1
]}

Tasdelen, Mehmet Atilla ^{[1
]}

Du Prez, Filip ^{[2
]}

Yagci, Yusuf ^{[1
]}

机构：

[1] Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey

[2] Univ Ghent, Dept Organ Chem, Polymer Chem Res Grp, B-9000 Ghent, Belgium

来源：

EUROPEAN POLYMER JOURNAL | 2008年 / 44卷 / 07期

关键词：

polymer/clay nanocomposites; intercalation; montmorillonite; chain transfer agent;

D O I：

10.1016/j.eurpolymj.2008.04.018

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In situ synthesis of poly(methyl methacrylate) (PMMA) and polystyrene (PS) nanocomposites by free radical polymerization using intercalated chain transfer agent (I-CTA) in the layers of montmorillonite (MMT) clay is reported. MMT clay was ion-exchanged with diethyl octyl ammonium ethylmercaptan bromide, which acts both as suitable intercalant and as chain transfer agent. These modified clays were then dispersed in methyl methacrylate (MMA) or styrene (St) monomers in different loading degrees to carry out the in situ free radical polymerization. The intercalation ability of the chain transfer agent and exfoliated nanocomposite structure were evidenced by both X-ray diffraction spectroscopy (XRD) and transmission electron microscopy (TEM). Thermal properties and morphologies of the resultant nanocomposites were also studied. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：1949 / 1954

页数：6

共 39 条

[1] Polymer-layered silicate nanocomposites: Preparation, properties and uses of a new class of materials [J].

Alexandre, Michael ;

Dubois, Philippe .

Materials Science and Engineering: R: Reports, 2000, 28 (1-2) :1-63

[2] SYNTHESIS AND PROPERTIES OF FLUORINATED TELECHELIC MACROMOLECULAR DIOLS PREPARED BY RADICAL GRAFTING OF FLUORINATED THIOLS ONTO HYDROXYL-TERMINATED POLYBUTADIENES [J].

AMEDURI, B ;

BOUTEVIN, B ;

NOUIRI, M .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1993, 31 (08) :2069-2080

[3] Organic/inorganic hybrids by 'living'/controlled ATRP grafting from layered silicates [J].

Böttcher, H ;

Hallensleben, ML ;

Nuss, S ;

Wurm, H ;

Bauer, J ;

Behrens, P .

JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (05) :1351-1354

[4]

Chapman H.D., 1965, METHODS SOIL ANAL CH, DOI DOI 10.2134/AGRONMONOGR9.2.C6

[5] SYNTHESIS OF CROWN ETHER-TERMINATED POLY(METHYL METHACRYLATE) BY RADICAL CHAIN TRANSFER POLYMERIZATION [J].

CHUJO, Y ;

NAKAMURA, T ;

YAMASHITA, Y .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1990, 28 (01) :59-65

[6] Polyimide nanocomposites prepared from high-temperature, reduced charge organoclays [J].

Delozier, DM ;

Orwoll, RA ;

Cahoon, JF ;

Ladislaw, JS ;

Smith, JG ;

Connell, JW .

POLYMER, 2003, 44 (08) :2231-2241

[7] Intergallery living polymerization using silicate-anchored photoiniferter. A versatile preparatory method for exfoliated silicate nanocomposites [J].

Di, JB ;

Sogah, DY .

MACROMOLECULES, 2006, 39 (03) :1020-1028

[8] Exfoliated block copolymer/silicate nanocomposites by one-pot, one-step in-situ living polymerization from silicate-anchored multifunctional initiator [J].

Di, Jianbo ;

Sogah, Dotsevi Y. .

MACROMOLECULES, 2006, 39 (15) :5052-5057

[9] Living anionic surface-initiated polymerization (LASIP) of styrene from clay nanoparticles using surface bound 1,1-diphenylethylene (DPE) initiators [J].

Fan, XW ;

Zhou, QY ;

Xia, CJ ;

Cristofoli, W ;

Mays, J ;

Advincula, R .

LANGMUIR, 2002, 18 (11) :4511-4518

[10] Synthesis of polystyrene-clay nanocomposites [J].

Fu, X ;

Qutubuddin, S .

MATERIALS LETTERS, 2000, 42 (1-2) :12-15

← 1 2 3 4 →