Synthesis and single crystal investigation of two-dimensional rectangular network [M(4,4′-bpy) (phth)(H2O)]n•2H2O with small neutral cavities

被引：104

作者：

Suresh, E ^{[1
]}

Boopalan, K ^{[1
]}

Jasra, RV ^{[1
]}

Bhadbhade, MM ^{[1
]}

机构：

[1] Cent Salt & Marine Chem Res Inst, Silicates & Catalysis Div, Bhavnagar 364002, Gujarat, India

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 16期

关键词：

D O I：

10.1021/ic000434v

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Synthesis and Single Crystal Investigation of Two-Dimensional Rectangular Network [M(4,4 ' -bpy) (Phth)(H2O)](n). 2H(2)O with Small Neutral Cavities Two isostructural neutral coordination polymers [M(4,4 ' -bpy)(phth)(H2O)]}(n)-2H(2)O, where M = Co2+, Cd2+, comprising rectangular grids with each cavity enclosed by two 4,4 ' -bipyridine (4,4 ' -bpy) and two phthalate (phth) ligands, which superpose in an offset fashion reducing the channel size to include two water molecules, have been synthesized and structurally characterized by single crystal X-ray diffraction.

引用

页码：4078 / +

页数：4

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