Electrophilic reactions of fluorocarbons under the action of aluminum chlorofluoride, a potent Lewis acid

被引：48

作者：

Petrov, VA

Krespan, CG

Smart, BE

机构：

[1] DuPont Ctrl. Res. and Development, Experimental Station, Wilmington, DE 19880-0328

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1996年 / 77卷 / 02期

关键词：

electrophilic reactions; fluorocarbons; aluminum chlorofluoride; Lewis acid; NMR spectroscopy;

D O I：

10.1016/0022-1139(96)03391-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new Lewis acid - aluminum chlorofluoride - was demonstrated to be an effective catalyst for the isomerization of fluoroolefins, polyfluorinated epoxides and cyclopropanes. At ambient temperature this catalyst converts perfluorobutadiene-1,3 into perfluorobutyne-2 and perfluoro(4-methylpentene-2) into perfluoro(2-methylpentene-2) in nearly quantitative yield. At 100 degrees C, aluminum chlorofluoride causes the cleavage of perfluorinated tertiary amines.

引用

页码：139 / 142

页数：4

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