Iridium complexes with secondary phosphines: Synthesis and X-ray crystal structure of [IrCl(Bu(2)(t)PH)(3)]

被引：9

作者：

Bottcher, HC

Graf, M

Merzweiler, K

机构：

[1] Department of Chemistry, Martin Luther University, Halle-Wittenberg, Kurt-Mothes-Str. 2

来源：

POLYHEDRON | 1997年 / 16卷 / 02期

关键词：

iridium; complex; mononuclear; secondary phosphines; crystal structure;

D O I：

10.1016/0277-5387(96)00289-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [{IrCl(COE)(2)}(2)] (1) (COE = cyclooctene) with Bu(2)(t)PH in hexane at room temperature gave the complex [IrCl(Bu(2)(t)PH)(3)] (2) which has been fully characterized by both spectroscopic and crystallographic methods. 1 reacts with carbon monoxide to give the Vaska-type complex trans-[IrCl(CO) (Bu(2)(t)PH)(2)] (3). Copyright (C) 1996 Elsevier Science Ltd

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页码：341 / 343

页数：3

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