On the atomic structure of Fe/Mn promoted sulfated zirconia

被引：10

作者：

Benaissa, M

Santiesteban, JG

Diaz, G

JoseYacaman, M

机构：

[1] AIR PROD & CHEM INC,ALLENTOWN,PA 18195

[2] UNIV NACL AUTONOMA MEXICO,INST FIS,MEXICO CITY 01000,DF,MEXICO

来源：

SURFACE SCIENCE | 1996年 / 364卷 / 02期

关键词：

high-resolution transmission electron microscopy; iron; manganese; sulfated zirconia; surface atomic structure;

D O I：

10.1016/0039-6028(96)00776-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The aim of the present work is to shed some light on the surface atomic structure of an Fe/Mn-promoted sulfated zirconia catalyst using high-resolution transmission electron microscopy (HRTEM) imaging. The presence of Fe and Mn species, which were found to be dispersed at a molecular level, were apparent on the {001} and {110} surfaces of zirconia particles. A combination of the present results with additional detailed studies using other physicochemical characterization techniques is needed to elucidate the atomic configuration of the active sites responsible for the enhanced catalytic activity of the Fe/Mn-promoted sulfated zirconia catalyst.

引用

页码：L591 / L594

页数：4

共 7 条

[1] ISOMERIZATION OF C-13 LABELED BUTANE OVER FE,MN PROMOTED SULFATED ZRO2 CATALYST [J].