Synthesis and structural characterization of Ln(III) complexes (Ln = Eu, Gd, Tb, Er, Tm, Lu) of tripodal tris[2-(salicylideneamino)ethyl]amine

被引:57
作者
Kanesato, M [1 ]
Yokoyama, T [1 ]
机构
[1] Tohoku Natl Ind Res Inst, Miyagino Ku, Sendai, Miyagi 9838551, Japan
关键词
D O I
10.1246/cl.1999.137
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The preparation and characterization of Ln(III) complexes (Ln = Eu, Gd, Tb, Er, Tm, Lu) of heptadentate (N4O3) ligand trensal, tris[2-(salicylideneamino)ethyl]amine (H3L1), have been studied. The molecular structures of [LnL(1)] were determined by X-ray structural analysis; these are heptadentate complexes in which the metal ions are coordinated by the three oxygen atoms and the four nitrogen atoms.
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页码:137 / 138
页数:2
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