Rate constants for the reaction of cumylperoxyl radicals with Bu3SnH and (TMS)3SiH

被引：12

作者：

Chatgilialoglu, C

Timokhin, VI

Zaborovskiy, AB

Lutsyk, DS

Prystansky, RE

机构：

[1] CNR, Icocea, I-40129 Bologna, Italy

[2] Natl Acad Sci Ukraine, Inst Phys Chem, Dept Physicochem, UA-290053 Lvov, Ukraine

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 05期

关键词：

D O I：

10.1039/a808894b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The rate constants for the reaction of a cumylperoxyl radical with Bu3SnH and (TMS)(3)SiH were determined at 72.5 degrees C to be 1600 and 66 M-1 s(-1), respectively, by using inhibited hydrocarbon oxidation methodologies.

引用

页码：405 / 406

页数：2

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