Single-wall carbon nanotube-ferrocene nanohybrids:: Observing intramolecular electron transfer in functionalized SWNTs

被引:172
作者
Guldi, DM [1 ]
Marcaccio, M
Paolucci, D
Paolucci, F
Tagmatarchis, N
Tasis, D
Vázquez, E
Prato, M
机构
[1] Univ Notre Dame, Radiat Lab, Notre Dame, IN 46556 USA
[2] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy
[3] Univ Trieste, Dipartimento Sci Farmaceut, I-34127 Trieste, Italy
关键词
carbon; electron transfer; fluorescence; nanotechnology; nanotubes;
D O I
10.1002/anie.200351289
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A long-lived charge-separated state, SWNT.--Fc.+, is formed by photoinduced electron transfer in a novel single-wall carbon nanotube-ferrocene (SWNT-Fc) nanohybrid. The presence of SWNT.-, detected by laser flash photolysis, was confirmed by time-resolved pulse radiolysis and steady-state bulk electrolysis.
引用
收藏
页码:4206 / 4209
页数:4
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