Novel high performance RTM bismaleimide resin with low cure temperature for advanced composites

被引:30
作者
Gu, AJ [1 ]
机构
[1] Zhejiang Univ, Inst Polymer Composites, Hangzhou 310027, Peoples R China
关键词
bismaleimide; resin transfer molding (RTM); composites; matrix; resins;
D O I
10.1002/pat.615
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A novel performance matrix, coded as LCRTM, with low cure and post-cure temperature (<= 200 degrees C) for fabricating advanced polymer composites via resin transfer molding (RTM), was successfully developed, made up of 4,4'-bismaleimidodiphenylmethane (BDM) and N-allyl diaminodipheny-lether (ADDE). Investigations show that the stoichiometry of BDM and ADDE has great effect on the processing and performance parameters of the resultant resins. In the case of the optimum formulation (the mole ratio of BDM and ADDE is 1:0.55), the injection temperature range is between 70-82 degrees C, and the pot life at 80 degrees C is 300 min, moreover, the cured resin has desirable thermal and mechanical properties after being cured at 200 degrees C for 6 hr, reflecting a great potential as high performance matrices for fabricating advanced composites via the RTM technique. Copyright (c) 2005 John Wiley & Sons, Ltd.
引用
收藏
页码:563 / 566
页数:4
相关论文
共 24 条
[1]  
ADVANI SG, 2001, POLYM MATRIX COMPOSI, P807
[2]  
Bao JW, 2001, CHINESE J POLYM SCI, V19, P53
[3]   Zirconium-mediated coupling reactions of amines and enol or allyl ethers:: Synthesis of allyl- and homoallylamines [J].
Barluenga, J ;
Rodríguez, F ;
Alvarez-Rodrigo, L ;
Zapico, JM ;
Fañanás, FJ .
CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (01) :109-116
[4]  
CHAUDHARI M, 1987, INT SAMPE S EXH P, V32, P24
[5]  
Esslinger JR, 2004, SAMPE J, V40, P9
[6]   Syntheses of an aromatic nitrile ether diamine and the bismaleimide bearing the diamine and the properties of their copolymers with 4,4′-bismaleimidodiphenylmethane (BMDPM) [J].
Fang, Q ;
Ding, XM ;
Wu, XY ;
Jiang, LX .
JOURNAL OF APPLIED POLYMER SCIENCE, 2002, 85 (06) :1317-1327
[7]   Electron-beam curing of thick thermoset composite matrices [J].
Glauser, T ;
Johansson, M ;
Hult, A .
POLYMER, 1999, 40 (19) :5297-5302
[8]   Thermal decomposition characteristics of Alder-ene adduct of diallyl bisphenol A novolac with bismaleimide: effect of stoichiometry, novolac molar mass and bismaleimide structure [J].
Gouri, C ;
Nair, CPR ;
Ramaswamy, R ;
Ninan, KN .
EUROPEAN POLYMER JOURNAL, 2002, 38 (03) :503-510
[9]  
Gu A., 1996, J NW POLYTECHN U, V14, P163
[10]   Preparation and properties of a novel high-performance resin system with low injection temperature for resin transfer moulding [J].
Gu, AJ ;
Liang, GZ .
POLYMER INTERNATIONAL, 2004, 53 (09) :1388-1393