Photocatalytic hydrogen production from a simple water-soluble [FeFe]-hydrogenase model system

被引：66

作者：

Cao, Wei-Ning

Wang, Feng

Wang, Hong-Yan

Chen, Bin

Feng, Ke

Tung, Chen-Ho

Wu, Li-Zhu ^{[1
]}

机构：

[1] Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 65期

基金：

中国国家自然科学基金;

关键词：

ELECTRON-TRANSFER;

D O I：

10.1039/c2cc33097k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Combined with a simple water soluble [FeFe]-hydrogenase mimic 1, Ru(bpy)(3)(2+) and ascorbic acid enable hydrogen production photocatalytically. More than 88 equivalents of H-2 were achieved in water, which is much better than that obtained in an organic solvent or a mixture of organic solvent and water.

引用

页码：8081 / 8083

页数：3

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