The solubility of methane in aqueous solutions of monoethanolamine, diethanolamine and triethanolamine

被引：35

作者：

Carroll, JJ

You, FY

Mather, AE ^{[1
]}

Otto, FD

机构：

[1] Univ Alberta, Dept Chem & Mat Engn, Edmonton, AB T6G 2G6, Canada

[2] Gas Liquids Engn Ltd, Calgary, AB T1Y 4T8, Canada

来源：

CANADIAN JOURNAL OF CHEMICAL ENGINEERING | 1998年 / 76卷 / 05期

关键词：

methane solubility; alkanolamines; Henry's law;

D O I：

10.1002/cjce.5450760512

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The solubility of methane in 3 kmol/m(3) solutions of monoethanolamine, diethanolamine, and triethanolamine was measured from 25 degrees to 125 degrees C and pressures up to about 13 MPa. Measurements were also made for the solubility of methane in water at 25 degrees to 125 degrees C and pressures up to 18 MPa in order to confirm the accuracy of the experimental technique. It is demonstrated that methane is more soluble tin terms of mole fraction) in the amine solution than in pure water. Furthermore, the solubility is an increasing function of the size of the alkanolamine. The solubility data were modeled using a Henry's-law approach and the results summarized in terms of salting-in coefficients.

引用

页码：945 / 951

页数：7

共 12 条

[1] A model for the solubility of light hydrocarbons in water and aqueous solutions of alkanolamines
Carroll, JJ
Mather, AE
[J]. CHEMICAL ENGINEERING SCIENCE, 1997, 52 (04) : 545 - 552
[2] PHASE-EQUILIBRIA IN THE SYSTEM WATER-METHYLDIETHANOLAMINE-PROPANE
CARROLL, JJ
JOU, FY
MATHER, AE
OTTO, FD
[J]. AICHE JOURNAL, 1992, 38 (04) : 511 - 520
[3] CULBERSON OL, 1951, T AM I MIN MET ENG, V192, P223
[4] DINGMAN JC, 1986, ANN AICHE M MIAM BEA
[5] SOLUBILITY OF NATURAL GASES IN AQUEOUS SALT SOLUTIONS .1. LIQUIDUS SURFACES IN THE SYSTEM CH4-H2O-NACL2-CACL2 AT ROOM TEMPERATURES AND AT PRESSURES BELOW 1000 PSIA
DUFFY, JR
SMITH, NO
NAGY, B
[J]. GEOCHIMICA ET COSMOCHIMICA ACTA, 1961, 24 (1-2) : 23 - 31
[6] VAPOR-LIQUID-EQUILIBRIA FOR ACID GASES AND LOWER ALKANES IN TRIETHYLENE GLYCOL
JOU, FY
DESHMUKH, RD
OTTO, FD
MATHER, AE
[J]. FLUID PHASE EQUILIBRIA, 1987, 36 : 121 - 140
[7] Phase equilibria in the system n-butane-water-methyldiethanolamine
Jou, FY
Carroll, JJ
Mather, AE
Otto, FD
[J]. FLUID PHASE EQUILIBRIA, 1996, 116 (1-2) : 407 - 413
[8] Solubility of ethane in aqueous solutions of triethanolamine
Jou, FY
Otto, FD
Mather, AE
[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1996, 41 (04) : 794 - 795
[9] HYDROCARBON GAS SOLUBILITY IN SWEETENING SOLUTIONS - METHANE AND ETHANE IN AQUEOUS MONOETHANOLAMINE AND DIETHANOLAMINE
LAWSON, JD
GARST, AW
[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1976, 21 (01) : 30 - 32
[10] Hydrocarbon gas solubility in sweetening solutions: Methane and ethane in aqueous monoethanolamine and diethanolamine - Comments
Mather, AE
Marsh, KN
[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1996, 41 (05) : 1210 - 1210

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