Studies towards the biomimetic synthesis of bisesquiterpene lactones

被引：26

作者：

Bagal, SK

Adlington, RM

Marquez, R

Cowley, AR

Baldwin, JE

机构：

[1] Univ Oxford, Dyson Perrins Lab, Dept Chem, Oxford OX1 3QY, England

[2] Univ Dundee, Dept Life Sci, Dundee DD1 5EH, Scotland

[3] Univ Oxford, Oxford OX1 3QR, England

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 27期

关键词：

D O I：

10.1016/S0040-4039(03)01172-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A possible biomimetic connection between atractylolide, hydroxyatractylolide and biatractylolide and biepiasterolide has been demonstrated by efficiently generating the biatractylolide and biepiasterolide core structures from atractylolide and hydroxyatractylolide model butenolides via a radicaloid intermediate in a single step in good yield. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：4993 / 4996

页数：4

共 22 条

[1]

Aresta M., 1969, INORG CHIM ACTA, V3, P227

[2]

FIESER LF, 1967, REAGENTS ORGANIC SYN, V1, P1171

[3] An instance of trivalent carbon triphenylmethyl [J].