Multiple addressing in a hybrid biphotochromic system

被引:63
作者
Frigoli, M [1 ]
Mehl, GH [1 ]
机构
[1] Univ Hull, Dept Chem, Kingston Upon Hull HU6 7RX, N Humberside, England
关键词
conjugation; molecular devices; photochemistry; photochromism; UV/Vis spectroscopy;
D O I
10.1002/anie.200462575
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Affairs of state: Investigation of the photochromic properties of a combined naphthopyran and diarylethene biphotochromic system (1) has revealed that four different states with entirely different absorption behaviors are formed. Opening of the naphthopyran ring leads to conjugation and electronic connection of both photochromes, while closure of the open diarylethene system extends the π-electron system over the whole molecule. (Chemical Equation Presented) © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:5048 / 5052
页数:5
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