Rare-earth iodides in ionic liquids:: The crystal structure of [SEt3]3[LnI6] (Ln = Nd, Sm)

被引:33
作者
Babai, A [1 ]
Mudring, AV [1 ]
机构
[1] Univ Cologne, Inst Anorgan Chem, D-50939 Cologne, Germany
关键词
D O I
10.1021/ic051533h
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Crystals of [SEt3](3)[Lnl(6)] (Ln = Nd, Sm) were obtained by the reaction of Lnl(2) with the ionic liquid [SEt3][Tf2N] [Tf2N = bis(trifluoromethanesulfonyl)imide]. The compounds are characterized by octahedral [Lnl(6)](3-) units that are surrounded by a distorted cube of triethylsulfonium cations.
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页码:8168 / 8169
页数:2
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