Nonmonotonic pattern of the critical percolation temperature due to variations of additive chain length in water-in-oil microemulsions

被引：2

作者：

Eicke, HF ^{[1
]}

Meier, W ^{[1
]}

机构：

[1] Univ Basel, Dept Chem, Inst Phys Chem, CH-4056 Basel, Switzerland

来源：

COLLOID AND POLYMER SCIENCE | 2001年 / 279卷 / 03期

关键词：

nonionic water-in-oil microemulsions nonmonotonic variation of critical percolation; temperature; alkyl chain length dependence of ionic additive on T-c; thermodynamic approach;

D O I：

10.1007/s003960000462

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The nonmonotonic variation of the critical percolation temperature (T-c) of ternary nonionic (C14E5) water-in-oil microemulsions was studied as a function of the alkyl chain length of an ionic additive (n-alkyl sulfonate sodium salt). A thermodynamic approach shows the relationship between T-c and additive chain length, which is supplemented by a consideration of a possible molecular mechanism of the observed phenomenon.

引用

页码：301 / 304

页数：4

共 16 条

[1]

[Anonymous], RENORMIERUNGSANSATZE

[2] PHENOMENOLOGICAL THEORIES OF GLOBULAR MICROEMULSIONS [J].

BORKOVEC, M .

ADVANCES IN COLLOID AND INTERFACE SCIENCE, 1992, 37 (3-4) :195-217

[3] POLYDISPERSITY IN DILUTE MICROEMULSIONS - A CONSEQUENCE OF THE MONOMER DROPLET EQUILIBRIUM [J].

BORKOVEC, M ;

EICKE, HF ;

RICKA, J .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1989, 131 (02) :366-381

[4] Charge transport in percolated water-in-oil microemulsions [J].

Eicke, HF ;

Thomas, H .

LANGMUIR, 1999, 15 (02) :400-404

[5] Interfacial charge transport in water-in-oil microemulsions stabilized by ionic-non-ionic surfactant mixtures [J].

Eicke, HF ;

Meier, W .

BIOPHYSICAL CHEMISTRY, 1996, 58 (1-2) :29-37

[6] THERMODYNAMICAL AND STATISTICAL CONSIDERATIONS ON SOME MICROEMULSION PHENOMENA [J].

EICKE, HF .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1977, 59 (02) :308-318

[7] PROBING ORDER PHENOMENA IN MACROFLUIDS BY PULSED ELECTRO-OPTICAL KERR EFFECT MEASUREMENTS [J].

EICKE, HF ;

HILFIKER, R ;

THOMAS, H .

CHEMICAL PHYSICS LETTERS, 1985, 120 (03) :272-275

[8]

EICKE HF, 1987, BER BUNSEN PHYS CHEM, V90, P872

[9] STUDY OF DYNAMICS OF MICROEMULSION DROPLETS BY NEUTRON SPIN-ECHO SPECTROSCOPY [J].

HUANG, JS ;

MILNER, ST ;

FARAGO, B ;

RICHTER, D .

PHYSICAL REVIEW LETTERS, 1987, 59 (22) :2600-2603

[10] MICROEMULSIONS WITH MIXTURES OF NONIONIC AND IONIC AMPHIPHILES [J].

KAHLWEIT, M ;

FAULHABER, B ;

BUSSE, G .

LANGMUIR, 1994, 10 (08) :2528-2532

← 1 2 →